{"id":21123,"date":"2022-10-28T08:40:27","date_gmt":"2022-10-28T08:40:27","guid":{"rendered":"https:\/\/peymantaeidi.net\/stem-cell\/?p=21123"},"modified":"2022-10-28T09:40:41","modified_gmt":"2022-10-28T09:40:41","slug":"tandem-perovskite-silicon-solar-cell-with-29-80-efficiency-via-periodic-nanotextures","status":"publish","type":"post","link":"https:\/\/peymantaeidi.net\/stem-cell\/2022\/10\/28\/tandem-perovskite-silicon-solar-cell-with-29-80-efficiency-via-periodic-nanotextures\/","title":{"rendered":"Tandem perovskite-silicon solar cell with 29.80% efficiency via periodic nanotextures"},"content":{"rendered":"
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Researchers from Germany have designed a tandem perovskite silicon PV cell that reportedly has lower reflection losses and improved open-circuit voltage. They demonstrated a device with submicrometre-periodic nanotextures and an improved back-reflector design.<\/p>\n<\/div>\n

October 27, 2022 Emiliano Bellini<\/a><\/span><\/div>\n

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A research group led by German research institute Helmholtz-Zentrum Berlin f\u00fcr Materialien und Energie GmbH has demonstrated a tandem perovskite-silicon solar cell based on submicrometre-periodic nanotextures and an improved back-reflector design.<\/p>\n

In the study \u201cNano-optical designs for high-efficiency monolithic perovskite\u2013silicon tandem solar cells<\/a>,\u201d published in nature nanotechnology<\/em>, the scientists explained that the gentle sinusoidal nanotexture that they used in the cell combines the advantages of structuring the silicon surface with maintaining high material quality of the solution-processed perovskite.<\/p>\n

\u201cWe show that the nanotexturing causes a substantial reduction of reflection losses compared to their planar counterpart, strongly improves the fabrication yield enabled by the excellent film formation properties and increases the open-circuit voltage by 15\u2009mV,\u201d they stated.<\/p>\n

By using ultraviolet nanoimprint lithography, reactive ion etching and wet chemical etching, the German group built the cell with a reflector with a dielectric buffer layer (RDBL) at the rear side of the silicon bottom cell and a sinusoidal nanostructure at the front surface.<\/p>\n

The team designed the tandem device with a passivated contact made with a layer of hydrogenated nanocrystalline silicon carbide (nc-SiC:H(n)), doped indium oxide as the transparent conducting oxide (TCO), a self-assembled monolayer of methyl-substi<\/span>tuted<\/span> carbazole (Me-4PACz) as the hole-transport layer, and a perovskite absorber. The silicon silicon bottom cell has a size of 2.5\u2009\u00d7\u20092.5\u2009cm2<\/sup> and a 1.1\u2009cm2<\/sup> contact area in the center.<\/p>\n

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\u201cThe RDBL comprises a silicon oxide (SiO2<\/sub>) buffer layer between the TCO and the silver back-reflector, reducing parasitic absorption losses. A silver grid covering 4% of the active area is screen-printed on top of the TCO before SiO2<\/sub> deposition to establish the electric contact between the TCO and Ag,\u201d they further explained.<\/p>\n

Experts from Germany’s Fraunhofer ISE CalLab<\/a> tested the performance of the solar cell and certified that it achieved a power conversion efficiency of 29.80%, an open-circuit voltage of 1.92\u2009V, a short-circuit current of 19.56\u2009mA\u2009cm\u22122<\/sup>, and a fill factor of 79.4%. The scientists said these short-circuit current levels, for both the perovskite top cell and the silicon bottom cell, are among the highest values reported in the literature for two-terminal tandem perovskite-silicon cells to date.<\/p>\n

\u201cA sensitivity analysis further indicates that the nanotextures substantially improve the performance robustness upon deviations from the optimal nanocrystalline silicon oxide layer thickness \u2014 an important aspect with regards to the industrialization of tandem technology and processing on larger areas,\u201d they concluded.<\/p>\n

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