{"id":28360,"date":"2022-12-06T00:54:28","date_gmt":"2022-12-06T01:54:28","guid":{"rendered":"https:\/\/peymantaeidi.net\/stem-cell\/?p=28360"},"modified":"2022-12-06T02:36:06","modified_gmt":"2022-12-06T02:36:06","slug":"x-rays-reveal-elusive-chemistry-for-better-ev-batteries","status":"publish","type":"post","link":"https:\/\/peymantaeidi.net\/stem-cell\/2022\/12\/06\/x-rays-reveal-elusive-chemistry-for-better-ev-batteries\/","title":{"rendered":"X-rays Reveal Elusive Chemistry for Better EV Batteries"},"content":{"rendered":"
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Newswise \u2014 UPTON, NY\u2014Researchers around the world are on a mission to relieve a bottleneck in the clean energy revolution: batteries<\/a>. From electric vehicles to renewable grid-scale energy storage, batteries are at the heart of society\u2019s most crucial green innovations\u2014but they need to pack more energy to make these technologies widespread and practical.<\/p>\n

Now, a team of scientists led by chemists at the U.S. Department of Energy\u2019s (DOE) Brookhaven National Laboratory and Pacific Northwest National Laboratory (PNNL) has unraveled the complex chemical mechanisms of a battery component that is crucial for boosting energy density: the interphase. Their work published today<\/a> in Nature Nanotechnology<\/em>.<\/p>\n

DOE\u2019s Battery500 consortium zeroes-in on lithium metal anodes<\/h3>\n

Many electronics, including smartphones and even electric vehicles, currently rely on conventional lithium-ion batteries<\/a>. While lithium-ion batteries have become common due to their high efficiency and long lifespan, these batteries face challenges in more demanding applications, such as powering electric vehicles over long distances.<\/p>\n

To build a better battery for electric vehicles, researchers across several national laboratories and DOE-sponsored universities have formed a consortium called Battery500<\/a>. Led by PNNL, the consortium aims to make battery cells with an energy density of 500 watt-hours per kilogram\u2014more than double the energy density of today\u2019s state-of-the-art batteries. To do so, the team is focusing on lithium metal batteries. While lithium-ion batteries rely on graphite anodes, these batteries use lithium metal anodes.<\/p>\n

Lithium metal anodes provide a much higher energy density than graphite anodes, but there are trade-offs. One of the biggest challenges scientists currently face is finding a way to stabilize the anode as the battery charges and discharges.<\/p>\n

In search of such a method, scientists at Brookhaven Lab and PNNL led an in-depth study on lithium metal batteries\u2019 solid-electrolyte interphase. The interphase is a chemical layer formed between the anode and the electrolyte as a battery charges and discharges. Scientists have learned that the interphase is the key to stabilizing lithium metal batteries, but it is a very sensitive sample with convoluted chemistry, making it difficult to study and, therefore, difficult to fully understand.<\/p>\n

\u201cThe interphase influences the cyclability of the whole battery. It\u2019s a very important, but elusive system,\u201d said Brookhaven chemist Enyuan Hu, who led the study. \u201cMany techniques can damage this small, sensitive sample, which also has both crystalline and amorphous phases.\u201d<\/p>\n

The scientific community has conducted many studies using a variety of experimental techniques, including cryo-electron microscopy, to better understand the interphase\u2014but the picture is still far from being clear and complete.<\/p>\n

\u201cA comprehensive understanding of the interphase provides the foundation for building an effective interphase,\u201d said PNNL scientist Xia Cao, who co-led the study and led the development of the electrolyte. \u201cThe Battery500 Consortium strongly encourages collaborations. We have been collaborating with Brookhaven Lab closely on many scientific projects, especially understanding the interphase.\u201d<\/p>\n

To dive deeper into the complex and elusive chemistry of the interphase, the team turned to a one-of-a-kind tool called the National Synchrotron Light Source II<\/a> (NSLS-II).<\/p>\n

NSLS-II shines light on interphase chemistry<\/h3>\n

NSLS-II is a DOE Office of Science User Facility at Brookhaven Lab that generates ultrabright x-rays for studying the atomic-scale makeup of materials. Hu and colleagues have been leveraging the advanced capabilities of the X-ray Powder Diffraction<\/a> (XPD) beamline at NSLS-II to make new discoveries in battery chemistry for many years. Building on their previous successes, the team returned to XPD to gather their most precise findings on the interphase yet.<\/p>\n

\u201cWe\u2019ve previously discovered<\/a> that high energy synchrotron x-rays do not damage the interphase sample,\u201d Hu said. \u201cThis is very important because one of the greatest challenges in characterizing the interphase is that the samples are highly sensitive to other types of radiation, including low energy x-rays. So in this work, we took advantage of two techniques that use high energy x-rays, x-ray diffraction and pair distribution function analysis, to capture the chemistries of both the crystalline and the amorphous phases in the lithium metal anode interphase.\u201d<\/p>\n

After cycling a lithium metal battery 50 times and harvesting enough interphase sample, the team disassembled the cell, scraped off a trace amount of interphase powder from the surface of the lithium metal, and directed XPD\u2019s high energy x-rays at the sample to reveal its convoluted chemistry.<\/p>\n

\u201cXPD is one of the few beamlines in the world that is capable of carrying out this research,\u201d said Sanjit Ghose, lead beamline scientist at XPD and a co-author of the study. \u201cThe beamline provided three advantages for this work: a small absorption cross section, which damages the sample less; combined techniques, x-ray diffraction to get the phase information and pair distribution function for real space information; and a high intensity beam for delivering quality data from a trace sample.\u201d<\/p>\n

This unique combination of advanced x-ray techniques provided the team with a detailed chemical map of the interphase components\u2014their origins, functionalities, interactions, and evolutions.<\/p>\n

\u201cWe focused on three different components of the interphase,\u201d said Brookhaven postdoc Sha Tan, first author of the paper. \u201cFirst was lithium hydride and its formation mechanism. We previously discovered that lithium hydride existed in the interphase, and this time we identified the hydrogen source.\u201d<\/p>\n

Specifically, the team identified that lithium hydroxide, which can be found natively in the lithium metal anode, is the likely contributor to lithium hydride. Controlling the composition of this compound will help scientists design an improved interphase with the highest performance possible.<\/p>\n

\u201cSecond, we studied lithium fluoride, which is very important for electrochemical performance, and found that it can be formed at a large scale in low concentration electrolytes,\u201d Tan said.<\/p>\n

Previously, scientists believed that lithium fluoride could only be formed in electrolytes using high concentration electrolytes, which rely on expensive salts. Thus, the work provides evidence that low concentration electrolytes, which are more cost effective, can potentially perform well in these battery systems.<\/p>\n

\u201cThird, we looked at lithium hydroxide to understand how it is consumed during battery cycling. These are all very new findings and important for understanding the interphase.\u201d<\/p>\n

Combined, these findings help shine a light on previously overlooked components of the interphase and will enable more accurate and controllable interphase design for lithium metal batteries.<\/p>\n

Moving forward, the team is continuing to contribute additional studies to the Battery500 consortium. Battery500 is currently in its second phase, which will continue through 2026.<\/p>\n

This work was supported by DOE\u2019s Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Office and DOE\u2019s Office of Science. Operations at NSLS-II are supported by the Office of Science.<\/p>\n

Brookhaven National Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov<\/p>\n

Follow @BrookhavenLab on Twitter<\/a> or find us on Facebook<\/a>.<\/em><\/p>\n

Pacific Northwest National Laboratory<\/a> draws on its distinguishing strengths in chemistry<\/a>, Earth sciences<\/a>, biology<\/a> and data science<\/a> to advance scientific knowledge and address challenges in sustainable energy<\/a> and national security<\/a>. Founded in 1965, PNNL is operated by Battelle for the Department of Energy\u2019s Office of Science, which is the single largest supporter of basic research in the physical sciences in the United States. DOE\u2019s Office of Science is working to address some of the most pressing challenges of our time. For more information, visit https:\/\/energy.gov\/science<\/a>. <\/em><\/p>\n

For more information on PNNL, visit PNNL’s News Center<\/a>. Follow us on Twitter<\/a>, Facebook<\/a>, LinkedIn<\/a> and Instagram<\/a>.<\/em><\/p>\n","protected":false},"excerpt":{"rendered":"

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