New class of materials has ‘no counterpart or analogue in nature’.
Northwestern University chemists have designed a new photonic lattice with properties never before seen in nature. In solid materials, atoms must be equally spaced apart and close enough together to interact effectively.
Now, new architectures based on stacked lattices of nanoparticles show interactions across unprecedentedly large distances.
Image credit: Northwestern University
When one lattice is stacked on top of the other, the nanoparticles can still interact with each other — even when the vertical separation among particles is 1,000 times the distance of the particle-to-particle spacing within the horizontal plane.
Because the nanoparticles can communicate across ultralong distances, the stacked architecture offers potential remote sensing and detection applications.
The study was published in the journal Nature Nanotechnology.
“This type of long-range coupling has not been observed before for any stacked periodic material,” said Teri Odom, a senior author of the study. “Other electronic or photonic stacked layers are separated vertically by a spacing similar to the horizontal periodicity of the building unit in the single layer. This is an entirely new class of engineered materials that have no counterpart or analogue in nature.”
A nanotechnology expert, Odom is chair of Northwestern’s chemistry department and the Joan Hustling Madden and William H. Madden Jr. Professor of Chemistry in the Weinberg College of Arts and Sciences. She also is a member of the International Institute of Nanotechnology and the Chemistry of Life Processes Institute. Northwestern co-authors include George Schatz, the Charles E. and Emma H. Morrison Professor of Chemistry at Weinberg.
To design the new material, Odom and her team took inspiration from moiré patterns, a geometrical design created by two patterns of identical periodic lattices.
The researchers first patterned photonic lattices consisting of two-dimensional arrays of nanoparticles with separations that promoted horizontal coupling, resulting in single-layer optical materials. Then, they stacked identical nanoparticle lattices on top of each other to create two-layered and multilayered lattices with new optical properties not accessible from one layer alone.
“We demonstrated that these stacked nanoparticle lattices can interact over ultralong distances by placing organic dye molecules around only one of the nanoparticle lattices in the stacked structure,” Odom said. “Then we optically excited the dye.”
The researchers discovered that by rotating one lattice relative to the other, they could change how the patterns interact with light. Depending on the twist angle, the stacked material could function as a nanolaser with emission at different angles. This insight opens new approaches to engineering nano-lasing characteristics. The direction and patterns of the moiré laser emission can be controlled in real time.
“This could be used to create new types of biomedical sensors,” said Jun Guan, the paper’s first author and a postdoctoral fellow in Odom’s laboratory.
“These devices can be designed to respond to changes in the body, providing important information about a patient’s health. A tiny change in the chemicals in the blood environment can cause changes in the way light bends around the photonic lattices. The moiré pattern will magnify this variation and read out by the corresponding laser emission angles.”
Source: Northwestern University
